(UN-2 6 a.)
Now spec. in phonetics: cf. ROUND v. 1 c. Also Unrounding vbl. sb.
1611. Cotgr., Desrondir, to vnround, vnbow, vncompasse.
1648. Hexham, II. Ontronden, to vnround, or take away the roundnesse of any thing.
1874. H. Sweet, in Trans. Philol. Soc., 471. Rounded front vowels are often unrounded. Ibid., 475. Rounding of back [vowels]; unrounding of front. Ibid. (1877), Handbk. Phonetics, 25. This vowel is best obtained by unrounding (u).