Chem. [f. TRI- 5 + SULPHONE.] A compound in which carbon radicals are linked to other carbon radicals by the intervention of three SO2, groups, the sulphur atoms being directly joined to the carbon atoms; e.g., triethylsulphonemethylmethane, C(CH3)(SO2.C2H5)3; trisulphone acetone,
(CH3)2C : {SO2C(CH3)2}2 : SO2. |
1874. Schorlemmer, Carbon Comp., 199. A series of sulphonic acids substitution products of marsh gas, the third is methenyltrisulphonic acid, CH(SO3H)3.
1879. Watts, Dict. Chem., VIII. I. 259. Benzenetrisulphonic acid, C6H3(SO3H)3 + 3 H2O, crystallises in long flat deliquescent needles.
1886. Jrnl. Chem. Soc., L. 623. Benzenetrisulphonic chloride melts at 184°; the amide melts at 306°. Ibid. (1892), LXII. 614. Attempts to prepare a tetrasulphone by the action of sodium on haloid trisulphones and of phenylthiochloride on trisulphonates [gave] negative results.